The spatial configurations and bonding effects of Oxides of Nitrogen were explained by using the Valence-shell Electron Repulsion Theory, Hybrid-orbital Theory and Molecular orbital Theory. 用杂化轨道理论和分子轨道理论阐明了氮的氧化物成键类型,给出了分子空间构型及结构数据的解释。
Now, from your book as well, this is the pz's of the two atomic orbitals forming the bonding orbital. 现在,也是你们书上,这是两个pz轨道,组成的成键轨道。
It turns out that the antibonding orbital is a little bit higher from the atomic orbital level than the bonding orbital is lower. 这证明了,反键轨道,比原子轨道高,成键轨道比原子轨道第。
So that's the idea of a bonding molecular orbital. 这就是成键分子轨道的概念。
Also, it is cylindrically symmetric around the bonding axis, so this is how we know that it's a sigma orbital. 此外,它关于键轴是圆柱对称的,这就是为什么我们知道它是sigma轨道。
And this again is what we're going to call a bonding orbital. 同样,我们叫它成键轨道。
So, let's start our discussion of a bonding orbital. 让我们开始来讨论成键轨道。
Through analysis on the structure of valence electron shell, the atom radius, the bonding orbital and other important parameters, this paper discusses the irregularity in the second circle of nonmetal elements and the irregular courses. 摘要本文通过对第二周期元素价电子层结构、原子半径、成键轨道及其重要参数的分析,讨论了第二周期非金属元素的不规则现象,并且分析了产生这些不规则性的原因。
And what you find is when you have a bonding orbital, the energy decreases compared to the atomic orbitals. 你们发现当你有个成键轨道的时候,相比原子轨道能量要降低。
And the other thing to point out is that the energy that an anti-bonding orbital is raised by, is the same amount as a bonding orbital is lowered by. 另外一个要指出的事情是,反键轨道引起的能量升高,和成键轨道引起的能量降低是相同的。
And so this lower level is called a bonding orbital, and it is a bonding molecular orbital. 所以能级较低的轨道叫做成键轨道,这就是成键分子轨道。
The 2 σ orbital of HF molecule is a strong bonding orbital, not nonbonding orbital and the result is in agreement with UPS spectrum of HF molecule. HF分子的2σ轨道是强成键分子轨道,而不是非键轨道,且与HF的光电子能谱相一致。
The Map Analysis of Bonding orbital Wave Function of Fe-Mo-S Cluster the Analogue of the Nitrogenase Fe-Mo-Cofactor 固氮酶Fe-Mo辅基模拟物Fe-Mo-S原子簇成键轨道的波函数图形分析
The valence bonding orbital rules in polyacids 多酸的价成键轨道规则
In this paper, the bonding behavior of 4f orbital in lanthanide coordination compounds was discussed and corresponding theory and research methods were summed up with 36 references. 本文介绍了目前国内外关于镧系配合物4f轨道成键行为研究的现状与进展,对其理论和研究方法进行了系统的总结,归纳了4f轨道的成键规律。
Mulliken population analysis shows that the electron transfer from the substrate to the anti-bonding orbital of adsorbed NO is the essential reason for the weakening of NO bond. Mulliken布居分析指出,底物电子向NO转移,并填充到NO的反键轨道上,从而导致NO键的削弱,并形成NO-。
The Bonding Energy Criterion of Molecular Orbital Bond Character and Bond Strength between Atoms 分子轨道成键性质及原子间化学键强度的成键能判据